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  • Title: Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers.
    Author: Jiang Y, Chan WC, Park CM.
    Journal: J Am Chem Soc; 2012 Mar 07; 134(9):4104-7. PubMed ID: 22332783.
    Abstract:
    An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields.
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