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  • Title: Dehydrogenative oxidation of alcohols in aqueous media using water-soluble and reusable Cp*Ir catalysts bearing a functional bipyridine ligand.
    Author: Kawahara R, Fujita K, Yamaguchi R.
    Journal: J Am Chem Soc; 2012 Feb 29; 134(8):3643-6. PubMed ID: 22339738.
    Abstract:
    A new catalytic system for the dehydrogenative oxidation of alcohols using a water-soluble Cp*Ir complex bearing a bipyridine-based functional ligand as catalyst has been developed. With this catalytic system, a variety of primary and secondary alcohols have been efficiently converted to aldehydes and ketones, respectively, in aqueous media without using any oxidant. Reuse of the catalyst by a very simple procedure has been also accomplished.
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