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Title: Helical polymer brushes with a preferred-handed helix-sense triggered by a terminal optically active group in the pendant. Author: Maeda K, Wakasone S, Shimomura K, Ikai T, Kanoh S. Journal: Chem Commun (Camb); 2012 Apr 04; 48(27):3342-4. PubMed ID: 22363934. Abstract: Helical polymer brushes with a preferred-handed helix-sense composed of a poly(phenylacetylene) backbone and poly(phenyl isocyanate) pendants are synthesized. The helix-sense of the backbone is effectively controlled by the helical chirality of the pendants, which is triggered by an optically active group introduced at the pendant terminal.[Abstract] [Full Text] [Related] [New Search]