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  • Title: Biomimetic total synthesis of (-)-isatisine A.
    Author: Wu W, Xiao M, Wang J, Li Y, Xie Z.
    Journal: Org Lett; 2012 Mar 16; 14(6):1624-7. PubMed ID: 22372625.
    Abstract:
    The biomimetic total synthesis of (-)-isatisine A, a novel alkaloid with an unprecedented fused tetracyclic skeleton, was accomplished in 8 steps from indole and 4,6-O-isopropylidene-protected glucal. The synthesis features a convergent synthetic strategy which relies on nucleophilic addition and a biomimetic benzilic ester rearrangement as key reactions.
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