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  • Title: Palladium(0)-catalyzed allylic alkylation of diketoester-dioxinones with allyl acetates under neutral conditions: synthesis of hexasubstituted benzene derivatives.
    Author: Cordes J, Laclef S, White AJ, Barrett AG.
    Journal: J Org Chem; 2012 Apr 06; 77(7):3524-30. PubMed ID: 22420647.
    Abstract:
    Intermolecular palladium(0)-catalyzed allylic alkylation of diketoester-dioxinones was performed under neutral conditions with 2-alkenyl and 2-cycloalkenyl acetates. Subsequent aromatization using cesium carbonate gave rise to isopropylidene-protected hexasubstituted resorcylates.
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