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  • Title: Construction of the azocane (azacyclooctane) moiety of the Lycopodium alkaloid lycopladine H via an intramolecular hydroaminomethylation strategy.
    Author: Sacher JR, Weinreb SM.
    Journal: Org Lett; 2012 Apr 20; 14(8):2172-5. PubMed ID: 22486178.
    Abstract:
    An efficient synthetic strategy has been developed for annulation of an azocane ring onto a bicyclo[2.2.2]octane scaffold via an intramolecular hydroaminomethylation protocol to generate an advanced intermediate bearing three of the four rings of the structurally unique Lycopodium alkaloid lycopladine H (1).
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