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  • Title: One-step synthesis of highly functionalized monofluorinated cyclopropanes from electron-deficient alkenes.
    Author: Ivashkin P, Couve-Bonnaire S, Jubault P, Pannecoucke X.
    Journal: Org Lett; 2012 May 04; 14(9):2270-3. PubMed ID: 22524490.
    Abstract:
    The unique combination of Zn/LiCl allowed generation of reactive zinc enolate from ethyl dibromofluoroacetate. This fluorinated enolate reacts efficiently with a wide range of functionalized electron-deficient alkenes to afford the corresponding monofluorinated cyclopropylcarboxylates in good yields.
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