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  • Title: Palladium-catalyzed asymmetric 6-endo cyclization of dienamides with substituent-driven activation.
    Author: Tsuchikawa H, Maekawa Y, Katsumura S.
    Journal: Org Lett; 2012 May 04; 14(9):2326-9. PubMed ID: 22530559.
    Abstract:
    Chiral 2-piperidinone compounds with various C-6 substituents were successfully synthesized via a Pd-catalyzed asymmetric 6-endo cyclization of dienamides, which were evidently activated by both N-p-toluenesulfonyl and C-3 ester substituents.
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