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  • Title: Pd-catalyzed domino carbonylative-decarboxylative allylation: an easy and selective monoallylation of ketones.
    Author: Giboulot S, Liron F, Prestat G, Wahl B, Sauthier M, Castanet Y, Mortreux A, Poli G.
    Journal: Chem Commun (Camb); 2012 Jun 14; 48(47):5889-91. PubMed ID: 22555554.
    Abstract:
    In the presence of an allyl alcohol, α-chloroacetophenones undergo an allyloxycarbonylation reaction followed by in situ decarboxylative allylation to selectively afford the corresponding monoallylated ketones via a Pd-catalyzed domino sequence. The scope of the reaction was extended to substituted α-chloroacetophenones as well as various allyl alcohols.
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