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  • Title: Formal asymmetric enone aminohydroxylation: organocatalytic one-pot synthesis of 4,5-disubstituted oxazolidinones.
    Author: Cruz DC, Sánchez-Murcia PA, Jørgensen KA.
    Journal: Chem Commun (Camb); 2012 Jun 21; 48(49):6112-4. PubMed ID: 22588517.
    Abstract:
    A formal asymmetric organocatalytic aminohydroxylation reaction of enones has been achieved via an aziridination-double S(N)2 sequence. As a part of the reaction design, the generated amino alcohol products are isolated as the corresponding oxazolidinones in good yields and excellent stereoselectivities.
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