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  • Title: Catalytic C-H amination with aromatic amines.
    Author: Gephart RT, Huang DL, Aguila MJ, Schmidt G, Shahu A, Warren TH.
    Journal: Angew Chem Int Ed Engl; 2012 Jun 25; 51(26):6488-92. PubMed ID: 22589147.
    Abstract:
    Aniline joins the club: A β-diketiminato copper(I) catalyst enables C-H amination of anilines employing low catalyst loadings to preclude oxidation to the diazene ArN=NAr. Electron-poor anilines are particularly resistant towards diazene formation and participate in the amination of strong and unactivated C-H bonds. N-alkyl anilines also take part in C-H amination.
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