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  • Title: Structural studies of the O-polysaccharide of Pragia fontium 97U124 containing 2-acetamido-2,4,6-trideoxy-4-(D-glyceroyl)amino-D-glucose.
    Author: Valueva OA, Zdorovenko EL, Varbanets LD, Shubchinskiy VV, Shashkov AS, Knirel YA.
    Journal: Carbohydr Res; 2012 Jul 01; 355():96-9. PubMed ID: 22591556.
    Abstract:
    The O-polysaccharide was obtained by acid hydrolysis of the lipopolysaccharide of Pragia fontium 97U124 and studied by sugar analysis and 1D and 2D NMR spectroscopy. A new bacillosamine derivative, 2-acetamido-2,4,6-trideoxy-4-(D-glyceroyl)amino-D-glucose (D-QuiNAc4NAcyl), was identified as a polysaccharide constituent. The following structure of the O-polysaccharide was established →3)-α-L-FucpNAc-(1→3)-α-L-FucpNAc-(1→3)-β-D-QuipNAc4NAcyl-(1→ This structure is closely related to that of the D-QuiNAc4NAc-containing O-polysaccharide of Pseudomonas aurantiaca IMV 31 established earlier (Knirel, Y. A.; Zdorovenko, G. M.; Veremeychenko, S. N.; Lipkind, G. M.; Shashkov, A. S.; Zakharova, I. Y.; Kochetkov, N. K. Bioorg. Khim.1988, 14, 352-358).
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