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  • Title: Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols.
    Author: Murugesan S, Jiang F, Achard M, Bruneau C, Dérien S.
    Journal: Chem Commun (Camb); 2012 Jul 04; 48(52):6589-91. PubMed ID: 22622865.
    Abstract:
    Intermolecular selective coupling of linear allylic alcohols and propargylic amides occurs in the presence of a catalytic amount of the cationic ruthenium complex [Cp*Ru(NCCH(3))(3)]PF(6) followed by condensation to generate six-membered cyclic enamides or hemiaminal ethers with water as the only side product.
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