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Title: Unexpected chiral induction from achiral cationic polythiophene aggregates and its application to the sugar pattern recognition. Author: Shiraki T, Dawn A, Tsuchiya Y, Yamamoto T, Shinkai S. Journal: Chem Commun (Camb); 2012 Jul 18; 48(56):7091-3. PubMed ID: 22683998. Abstract: The aggregates of a cationic polythiophene (PT1) formed in poor solvent in the presence of sugars showed the distinct circular dichroism activity, the intensity being well correlated with the specific optical rotation [α] of sugars: therefore, the present system is useful as a novel sugar structure reading-out method.[Abstract] [Full Text] [Related] [New Search]