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  • Title: Nickel-catalyzed reductive coupling of aryl halides with secondary alkyl bromides and allylic acetate.
    Author: Wang S, Qian Q, Gong H.
    Journal: Org Lett; 2012 Jul 06; 14(13):3352-5. PubMed ID: 22697415.
    Abstract:
    A room-temperature Ni-catalyzed reductive method for the coupling of aryl bromides with secondary alkyl bromides has been developed, providing C(sp(2))-C(sp(3)) products in good to excellent yields. Slight modification of this protocol allows efficient coupling of activated aryl chlorides with cyclohexyl bromide and aryl bromides with allylic acetate.
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