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  • Title: Indolocarbazole-based ligands for ladder-type four-coordinate boron complexes.
    Author: Curiel D, Más-Montoya M, Usea L, Espinosa A, Orenes RA, Molina P.
    Journal: Org Lett; 2012 Jul 06; 14(13):3360-3. PubMed ID: 22716949.
    Abstract:
    A novel class of π-conjugated systems, which combine the indolo[3,2-b]carbazole unit with the formation of four-coordinate boron complexes, is presented. The resulting conjugated compounds have a double-laddered structure that provides interesting optical and electrochemical properties. The wide absorption range, covering most of the visible spectrum, along with the narrowing of the HOMO-LUMO energy gap, due to the presence of diphenylboryl centers, reinforces the potential of these molecules within the area of organic electronics.
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