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  • Title: Preparation, characterization and catalytic properties of Pd-Fe-zeolite and Pd-Ce-zeolite composite catalysts.
    Author: Bi YS, Dang GY, Zhao XH, Meng XF, Lu HJ, Jin JT.
    Journal: J Hazard Mater; 2012 Aug 30; 229-230():245-50. PubMed ID: 22727393.
    Abstract:
    Highly effective composite catalysts for removal of CO by catalytic oxidation have been designed through constructing active centers on the support of zeolite. Performances of the derived Pd-Fe-zeolite and Pd-Ce-zeolite composite catalysts for CO removal under different heterogeneous conditions were studied. The results indicate that the two kinds of promoted catalysts, including special chemical states of Pd and surface active oxygen, show high catalytic activities not only for the low temperature oxidation of CO, but also for CO electro-oxidation. The typical light-off temperatures of Pd-Fe-zeolite and Pd-Ce-zeolite for low temperature CO oxidation are 270 and 273 K. Their characteristic peak potentials for CO electro-oxidation are both around 0.70 V. The promotional effects are associated with the special interaction among Pd, modifier and zeolite, which can be firmly supported by the detailed characterizations using XRD, BET, XPS, TPD and TPR.
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