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  • Title: Synthesis and self-assembly of "tree-like" amphiphilic glycopolypeptides.
    Author: Bonduelle C, Huang J, Ibarboure E, Heise A, Lecommandoux S.
    Journal: Chem Commun (Camb); 2012 Aug 28; 48(67):8353-5. PubMed ID: 22792543.
    Abstract:
    Novel synthetic tree-like oligosaccharides-grafted-polypeptides were prepared by using Huisgen 1,3-dipolar cycloaddition between poly(γ-benzyl-L-glutamate)-block-poly(propargylglycine) and two different oligosaccharides, dextran or hyaluronan. By direct solubilisation in water, these tree-like glycopeptides spontaneously form very small assemblies with sizes below 50 nm and low polydispersity.
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