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  • Title: Total synthesis of (±)-pallambins C and D.
    Author: Xu XS, Li ZW, Zhang YJ, Peng XS, Wong HN.
    Journal: Chem Commun (Camb); 2012 Sep 04; 48(68):8517-9. PubMed ID: 22820708.
    Abstract:
    The first total synthesis of (±)-pallambins C and D has been accomplished in a linear 38 step reaction from (±)-Wieland-Miescher ketone. The key conversions are featured as follows: a Grob fragmentation-intramolecular aldol cyclization and a thiourea/palladium-catalyzed carbonylative annulation.
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