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  • Title: Organic acid induced olefination reaction of lactones.
    Author: Yanai H, Taguchi T.
    Journal: Chem Commun (Camb); 2012 Sep 14; 48(71):8967-9. PubMed ID: 22850596.
    Abstract:
    (Z)-Selective olefination of several lactones with ketene silyl acetals was achieved by the catalysis of carbon acids (C-H acids) having a bis(triflyl)methyl group as an acidic functionality; in particular, the triple carbon acid having three bis(triflyl)methyl groups in phloroglucinol shows an excellent catalytic performance.
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