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  • Title: A nitroolefin functionalized BODIPY chemodosimeter for biothiols driven by an unexpected conjugated addition mechanism.
    Author: Zhang M, Wu Y, Zhang S, Zhu H, Wu Q, Jiao L, Hao E.
    Journal: Chem Commun (Camb); 2012 Sep 14; 48(71):8925-7. PubMed ID: 22850630.
    Abstract:
    A weakly fluorescent nitroolefin functionalized BODIPY 1 was prepared and rapidly reacted with thiols through an unexpected conjugated addition to the azafulvene ring of BODIPY to generate highly fluorescent BODIPYs 4 and 5. This reaction was applied for the highly selective and sensitive detection of Cys in living cells.
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