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  • Title: A versatile ruthenium(II)-NNC complex catalyst for transfer hydrogenation of ketones and Oppenauer-type oxidation of alcohols.
    Author: Du W, Wang L, Wu P, Yu Z.
    Journal: Chemistry; 2012 Sep 10; 18(37):11550-4. PubMed ID: 22887575.
    Abstract:
    A ruthenium(II)-NNC pincer complex containing an unsymmetrical tridentate pyrazolyl-pyridyl-tolyl ligand was synthesized and structually characterized. This complex exhibited excellent catalytic activity for the transfer hydrogenation of ketones in 2-propanol at reflux, and for the Oppenauer-type dehydrogenative oxidation of alcohols in acetone at reflux (see scheme).
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