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  • Title: Total synthesis of (-)-quinocarcin by gold(I)-catalyzed regioselective hydroamination.
    Author: Chiba H, Oishi S, Fujii N, Ohno H.
    Journal: Angew Chem Int Ed Engl; 2012 Sep 03; 51(36):9169-72. PubMed ID: 22890756.
    Abstract:
    In control: The novel and enantioselective total synthesis of (-)-quinocarcin includes the highly stereoselective preparation of the 2,5-cis-pyrrolidine by intramolecular amination, a selective substrate-controlled 6-endo-dig intramolecular alkyne hydroamination with a cationic Au(I) catalyst, and Lewis-acid-mediated ring-opening/halogenation sequence.
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