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  • Title: Palladium-catalyzed cross-coupling reactions of electron-deficient alkenes with N-tosylhydrazones: functional-group-controlled C-C bond construction.
    Author: Jiang H, Fu W, Chen H.
    Journal: Chemistry; 2012 Sep 17; 18(38):11884-8. PubMed ID: 22890989.
    Abstract:
    In the zone: A palladium-catalyzed cross-coupling reaction of electron-deficient alkenes with N-tosylhydrazones, which affords diverse C-C bonds resulting from the functional-group-controlled effect, is reported (see scheme). These cascade transformations present remarkable stereoselectivity and a high synthetic potential. The presence of water substantially promotes both reaction routes.
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