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  • Title: Total synthesis of (-)-irciniastatin B and structural confirmation via chemical conversion to (+)-irciniastatin A (psymberin).
    Author: An C, Hoye AT, Smith AB.
    Journal: Org Lett; 2012 Sep 07; 14(17):4350-3. PubMed ID: 22892009.
    Abstract:
    The total synthesis and structural confirmation of the marine sponge cytotoxin (-)-irciniastatin B has been achieved via a unified strategy employing a late-stage, selective deprotection/oxidation sequence that provides access to both (+)-irciniastatin A (psymberin) and (-)-irciniastatin B.
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