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  • Title: Chemoselective palladium-catalyzed α-allylation of α-boryl aldehydes.
    Author: St Denis JD, He Z, Yudin AK.
    Journal: Org Biomol Chem; 2012 Oct 21; 10(39):7900-2. PubMed ID: 22911058.
    Abstract:
    Herein we report the development of an α-allylation reaction of α-boryl aldehydes that preserves the carbon-boron bond under Pd(0)/Pd(II) catalysis. A variety of α-boryl aldehydes and allylic alcohols participate in this chemoselective transformation. The α-allylated products were obtained as single regioisomers.
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