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  • Title: The selective synthesis of metallanucleosides and metallanucleotides: a new tool for the functionalization of nucleic acids.
    Author: Martín-Ortíz M, Gómez-Gallego M, Ramírez de Arellano C, Sierra MA.
    Journal: Chemistry; 2012 Oct 01; 18(40):12603-8. PubMed ID: 22933336.
    Abstract:
    Nucleobases team up: the efficient and selective preparation of purine-derived metallanucleosides, metallanucleotides, and metalladinucleotides having M-C bonds (M=Ir(III), Rh(III)) is reported for the first time. The results presented may be applied to the synthesis of functionalized nucleic acids, or DNA/RNA-modified segments.
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