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  • Title: Cationic ruthenium catalysts for alkyne annulations with oximes by C-H/N-O functionalizations.
    Author: Kornhaaß C, Li J, Ackermann L.
    Journal: J Org Chem; 2012 Oct 19; 77(20):9190-8. PubMed ID: 22978404.
    Abstract:
    Cationic ruthenium(II) complexes enabled efficient redox-neutral annulations of alkynes with readily available oximes. The catalytic dehydrative C-H/N-O bond functionalization proved to be broadly applicable and was shown to proceed through a reversible cyclometalation.
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