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Title: Cationic ruthenium catalysts for alkyne annulations with oximes by C-H/N-O functionalizations. Author: Kornhaaß C, Li J, Ackermann L. Journal: J Org Chem; 2012 Oct 19; 77(20):9190-8. PubMed ID: 22978404. Abstract: Cationic ruthenium(II) complexes enabled efficient redox-neutral annulations of alkynes with readily available oximes. The catalytic dehydrative C-H/N-O bond functionalization proved to be broadly applicable and was shown to proceed through a reversible cyclometalation.[Abstract] [Full Text] [Related] [New Search]