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  • Title: Transmetallation between metal-only Lewis pairs: a new rhodium alane complex.
    Author: Bauer J, Braunschweig H, Radacki K.
    Journal: Chem Commun (Camb); 2012 Oct 28; 48(84):10407-9. PubMed ID: 22990068.
    Abstract:
    In this communication, synthesis of a rhodium alane Lewis adduct, [Cp(Me(3)P)(2)Rh→AlCl(3)], is reported. Given that direct synthesis using aluminium trichloride failed, a convenient transmetallation reaction was applied. The new MOLP was analysed by single crystal X-ray diffraction, multinuclear NMR spectroscopy and density functional theory calculations.
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