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  • Title: Total synthesis of debromoflustramines B and E based on the intramolecular carbamoylketene-alkene [2 + 2] cycloaddition.
    Author: Ozawa T, Kanematsu M, Yokoe H, Yoshida M, Shishido K.
    Journal: J Org Chem; 2012 Oct 19; 77(20):9240-9. PubMed ID: 23013172.
    Abstract:
    Total synthesis of debromoflustramines B and E has been accomplished by using a platinum-catalyzed addition reaction of o-aminophenylboronic acid with the allene and an intramolecular carbamoylketene-alkene [2 + 2] cycloaddition for the construction of the basic carbon framework of the target alkaloids as the key steps.
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