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  • Title: General switch in regioselectivity in the Mukaiyama aldol reaction of silyloxyfuran with aldehydes in aqueous solvents.
    Author: Woyciechowska M, Forcher G, Buda S, Mlynarski J.
    Journal: Chem Commun (Camb); 2012 Nov 18; 48(89):11029-31. PubMed ID: 23037879.
    Abstract:
    An unexpected yet disciplined course of catalytic Mukaiyama-aldol reaction instead of the expected vinylogous Mukaiyama-aldol reaction has been observed for the reaction of silyloxyfuran with various aldehydes under Lewis acid catalytic control in water-containing solvents.
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