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  • Title: Copper- and phosphine-ligand-free palladium-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides.
    Author: Yu YB, Fan S, Zhang X.
    Journal: Chemistry; 2012 Nov 12; 18(46):14643-8. PubMed ID: 23055245.
    Abstract:
    Simply id(all)ylic: a copper- and phosphine-ligand-free Pd-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides and the reaction mechanism are described. The simple catalytic system, broad substrate scope, and excellent functional-group compatibility of this protocol provides a useful and facile access to allylated polyfluoroarenes.
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