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  • Title: CuAAC click functionalization of azide-modified nanodiamond with a photoactivatable CO-releasing molecule (PhotoCORM) based on [Mn(CO)3(tpm)]+.
    Author: Dördelmann G, Meinhardt T, Sowik T, Krueger A, Schatzschneider U.
    Journal: Chem Commun (Camb); 2012 Dec 07; 48(94):11528-30. PubMed ID: 23090687.
    Abstract:
    The copper-catalyzed 1,3-dipolar azide-alkyne cycloaddition (CuAAC) was used for the first time to attach a biologically active carbon monoxide delivery agent to modified nanodiamond (ND) as a highly biocompatible carrier. The [Mn(CO)(3)(tpm)](+) photoactivatable CO-releasing molecule (PhotoCORM) on the surface retained the carbon monoxide release properties of the parent compound as shown with the myoglobin assay.
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