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  • Title: Alternated stacks of nonpolar oligo(p-phenyleneethynylene)-BODIPY systems.
    Author: Florian A, Mayoral MJ, Stepanenko V, Fernández G.
    Journal: Chemistry; 2012 Nov 19; 18(47):14957-61. PubMed ID: 23097323.
    Abstract:
    Supramolecular chemistry: The self-assembly of an oligo(p-phenyleneethynylene)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (OPE-BODIPY) system into alternated 1D π stacks in solution exhibited liquid-crystalline properties at room temperature. This system represents a new approach towards a controlled dye organization exclusively driven by π-π interactions (see figure).
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