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  • Title: Vanadium-catalyzed enantioselective Friedel-Crafts-type reactions.
    Author: Takizawa S, Arteaga Arteaga F, Yoshida Y, Kodera J, Nagata Y, Sasai H.
    Journal: Dalton Trans; 2013 Sep 07; 42(33):11787-90. PubMed ID: 23103937.
    Abstract:
    Vanadium-mediated enantioselective Friedel-Crafts (FC)-type reactions were established using the dinuclear vanadium complex (R(a),S,S)-1a. The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities.
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