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  • Title: Catalytic enantioselective allylic amination of unactivated terminal olefins via an ene reaction/[2,3]-rearrangement.
    Author: Bao H, Tambar UK.
    Journal: J Am Chem Soc; 2012 Nov 14; 134(45):18495-8. PubMed ID: 23106555.
    Abstract:
    The enantioselective allylic amination of unactivated terminal olefins represents a direct and attractive strategy for the synthesis of enantioenriched amines. We have developed the first use of a nitrogen-containing reagent and a chiral palladium catalyst to convert unfunctionalized olefins into enantioenriched allylic amines via an ene reaction/[2,3]-rearrangement.
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