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Title: A highly active catalytic system for Suzuki-Miyaura cross-coupling reactions of aryl and heteroaryl chlorides in water. Author: Mao SL, Sun Y, Yu GA, Zhao C, Han ZJ, Yuan J, Zhu X, Yang Q, Liu SH. Journal: Org Biomol Chem; 2012 Dec 21; 10(47):9410-7. PubMed ID: 23111458. Abstract: An easily available Pd(OAc)(2)/(2-mesitylindenyl)dicyclohexylphosphine/Me(octyl)(3)N(+)Cl(-)/K(3)PO(4)·3H(2)O catalytic system was developed and it shows high catalytic activity in the Suzuki-Miyaura cross-coupling reaction of a diverse array of aryl and heteroaryl chlorides in water. Notably, this catalytic system also works with ultra-low loading of the catalyst with high turnover numbers.[Abstract] [Full Text] [Related] [New Search]