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  • Title: Highly cis-selective synthesis of iodo-aziridines using diiodomethyllithium and in situ generated N-Boc-imines.
    Author: Bull JA, Boultwood T, Taylor TA.
    Journal: Chem Commun (Camb); 2012 Dec 28; 48(100):12246-8. PubMed ID: 23149421.
    Abstract:
    The first preparation of iodoaziridines is described. The addition of diiodomethyllithium to N-Boc-imines affords these novel aziridines in high yields. The reaction proceeds in one-pot via a highly diastereoselective cyclisation of an amino gem-diiodide intermediate.
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