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  • Title: Highly stereoselective glycosyl-chloride-mediated synthesis of 2-deoxyglucosides.
    Author: Verma VP, Wang CC.
    Journal: Chemistry; 2013 Jan 14; 19(3):846-51. PubMed ID: 23233443.
    Abstract:
    Cl intermediates: The glycosylation of per-O-benzylated 2-deoxy- and 2,6-dideoxythioglycosides, promoted by the combination of para-toluenesulfenyl chloride (p-TolSCl) and silver triflate (AgOTf), furnished the products in high yields and high stereoselectivity. The glycosyl chloride was the intermediate (see scheme).
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