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  • Title: Enantioseparations by capillary electrophoresis using cyclodextrins as chiral selectors.
    Author: Scriba GK, Jáč P.
    Journal: Methods Mol Biol; 2013; 970():271-87. PubMed ID: 23283784.
    Abstract:
    Due to their commercial availability, cyclodextrins are the most frequently used chiral selectors in capillary electrophoresis as documented by the numerous publications in the field. A variety of migration modes can be realized depending on the characteristics of the cyclodextrins and the analytes. The basic considerations regarding the development of a chiral CE method employing cyclodextrins as chiral selectors are briefly discussed. The presented examples illustrate the separation modes of an acidic and a basic analyte with native and charged cyclodextrin derivatives as a function of the pH of the background electrolyte and the cyclodextrin concentration.
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