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  • Title: Enantioselective formal aza-Diels-Alder reactions of enones with cyclic imines catalyzed by primary aminothioureas.
    Author: Lalonde MP, McGowan MA, Rajapaksa NS, Jacobsen EN.
    Journal: J Am Chem Soc; 2013 Feb 06; 135(5):1891-4. PubMed ID: 23321009.
    Abstract:
    A highly enantio- and diastereoselective synthesis of indolo- and benzoquinolizidine compounds has been developed through the formal aza-Diels-Alder reaction of enones with cyclic imines. This transformation is catalyzed by a new bifunctional primary aminothiourea that achieves simultaneous activation of both the enone and imine reaction components.
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