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  • Title: Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution.
    Author: Nugent P, Rhodus V, Pham T, Tudor B, Forrest K, Wojtas L, Space B, Zaworotko M.
    Journal: Chem Commun (Camb); 2013 Feb 25; 49(16):1606-8. PubMed ID: 23340547.
    Abstract:
    Pillar substitution in a long-known metal-organic material with saturated metal centres, [Cu(bipy)(2)(SiF(6))](n), has afforded the first crystallographically characterized porous materials based upon TiF(6)(2-) and SnF(6)(2-) anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO(2)vs. CH(4) and N(2).
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