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  • Title: Asymmetric intermolecular conjugate addition of amino acid derivatives via memory of chirality: total synthesis of manzacidin A.
    Author: Yoshimura T, Kinoshita T, Yoshioka H, Kawabata T.
    Journal: Org Lett; 2013 Feb 15; 15(4):864-7. PubMed ID: 23350911.
    Abstract:
    Asymmetric intermolecular conjugate addition of α-amino acid derivatives with 4 via memory of chirality has been developed. The reactions proceeded in up to 98% ee with retention of configuration at the newly formed tetrasubstituted carbon center when R = Me. The product (R = Me) was transformed into manzacidin A.
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