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  • Title: Anodic electrogenerated chemiluminescence behavior of graphite-like carbon nitride and its sensing for rutin.
    Author: Cheng C, Huang Y, Wang J, Zheng B, Yuan H, Xiao D.
    Journal: Anal Chem; 2013 Mar 05; 85(5):2601-5. PubMed ID: 23373468.
    Abstract:
    In this paper, the anodic electrogenerated chemiluminescence (ECL) behavior of graphite-like carbon nitride (g-C3N4) is studied using cyclic voltammetry with triethanolamine (TEA) as a coreactant. The possible anodic ECL response mechanism of the g-C3N4/TEA system is proposed. Furthermore, it is observed that the anodic ECL signal can be quenched efficiently in the presence of rutin, on the basis of which a facile anodic ECL senor for the determination of rutin is developed. This ECL sensor is found to have a linear response in the range of 0.20-45.0 μM and a low detection limit of 0.14 μM (at signal-to-noise of 3). These results suggest that semiconductor g-C3N4 has great potential in extending the application in the ECL field as an efficient luminophore.
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