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  • Title: Ru-catalyzed synthesis of dihydrofuroquinolines from azido-cyclopropyl ketones.
    Author: Yang W, Xu L, Chen Z, Zhang L, Miao M, Ren H.
    Journal: Org Lett; 2013 Mar 15; 15(6):1282-5. PubMed ID: 23432000.
    Abstract:
    An efficient Ru-catalyzed synthesis of dihydrofuroquinolines from azido-cyclopropyl ketones via the reduction-cyclization-rearrangement process is reported. A plausible reaction mechanism for this process is depicted. Additionally, when the reaction was carried out under H2 (1 atm) in the presence of Pd/C, 4-quinolones were obtained in excellent yields.
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