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  • Title: A catalytic multicomponent coupling reaction for the enantioselective synthesis of spiroacetals.
    Author: Cala L, Mendoza A, Fañanás FJ, Rodríguez F.
    Journal: Chem Commun (Camb); 2013 Apr 04; 49(26):2715-7. PubMed ID: 23435368.
    Abstract:
    The first multicomponent catalytic asymmetric synthesis of spiroacetals has been described. Hybrid molecules comprising a spiroacetal scaffold (a natural-product inspired scaffold) and an α-amino acid motif (a privileged fragment) are easily available through a gold phosphate-catalysed one-pot three component coupling reaction of alkynols, anilines and glyoxylic acid.
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