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  • Title: Syntheses of the C1-C14 and C15-C25 fragments of amphidinolide C.
    Author: Wu D, Forsyth CJ.
    Journal: Org Lett; 2013 Mar 15; 15(6):1178-81. PubMed ID: 23441846.
    Abstract:
    Divergent syntheses of the C1-C14 and C15-C25 fragments of amphidinolide C have been achieved. The synthesis of the C15-C25 fragment featured cobalt-catalyzed modified Mukaiyama aerobic alkenol cyclization and sulfur-directed regiocontrolled Wacker oxidation of an internal alkene. The C1-C14 fragment was established by alkenyllithium addition to an aldehyde followed by a challenging olefination of a highly inert C9 ketone.
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