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  • Title: Aluminum, gallium, germanium, copper, and phosphorus complexes of meso-triaryltetrabenzocorrole.
    Author: Pomarico G, Nardis S, Naitana ML, Vicente MG, Kadish KM, Chen P, Prodi L, Genovese D, Paolesse R.
    Journal: Inorg Chem; 2013 Apr 01; 52(7):4061-70. PubMed ID: 23480825.
    Abstract:
    5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV-vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the π-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.
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