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  • Title: Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid.
    Author: Villa A, Schiavoni M, Campisi S, Veith GM, Prati L.
    Journal: ChemSusChem; 2013 Apr; 6(4):609-12. PubMed ID: 23495091.
    Abstract:
    Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.
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