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  • Title: Direct access to benzo[b]furans through palladium-catalyzed oxidative annulation of phenols and unactivated internal alkynes.
    Author: Kuram MR, Bhanuchandra M, Sahoo AK.
    Journal: Angew Chem Int Ed Engl; 2013 Apr 22; 52(17):4607-12. PubMed ID: 23526675.
    Abstract:
    2,3-Disubstituted benzo[b]furans are prepared in one step from commercially available phenols and readily accessible unactivated internal alkynes (see scheme). This Pd-catalyzed oxidative annulation has a broad substrate scope and allows access to a wide range of benzo[b]furans.
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